Issue 4, 2000
From the journal:

Chemical Communications

Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide

Tjerk J. de Vries,*a   Robbert Duchateau,b   Marius A. G. Vorstmana  and  Jos T. F. Keurentjesa  

* Corresponding authors

a Process Development Group, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, PO Box 513, Eindhoven, The Netherlands.
E-mail: t.de.vries@tue.nl

b Dutch Polymer Institute, PO Box 902, Eindhoven, The Netherlands

c Schuit Institute of Catalysis, Eindhoven University of Technology, PO Box 513, Eindhoven, The Netherlands

Abstract

A late transition metal catalyst has been used to polymerise hex-1-ene and ethene in supercritical carbon dioxide, yielding high molecular weight polymers; a comparison with polymerisations in CH2Cl2 reveal that polymers with identical molecular weight and polydispersity are formed.

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Article information

DOI
https://doi.org/10.1039/A908966G
Article type
Communication
Submitted
11 Nov 1999
Accepted
06 Jan 2000
First published
07 Feb 2000

Chem. Commun., 2000, 263-264

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Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide

T. J. D. Vries, R. Duchateau, M. A. G. Vorstman and J. T. F. Keurentjes, Chem. Commun., 2000, 263 DOI: 10.1039/A908966G

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