Issue 5, 2000
From the journal:

Chemical Communications

cis-Trihydrogen cyclotriphosphazenates—acidic anions in strongly basic media

Gavin T. Lawson,a   Frederic Rivals,a   Mathieu Tascher,a   Chacko Jacob,a   Jamie F. Bickleya  and  Alexander Steiner*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: A.Steiner@liv.ac.uk

Abstract

Exclusively cis-protonation occurs at axial N-atoms of chair shaped P3N9 ring cores in the protolysis of the lithium salt of hexaanionic cyclotriphosphazenate [(CyN)6P3N3]6− with three equivalents of butan-1-ol and cis-deprotonation takes place at the hexaprotic cyclotriphosphazene (PhNH)6P3N3 with three equivalents of BunLi, respectively, yielding both times lithium salts of cis-trihydrogen cyclotriphosphazenates [(RNH)3(RN)3P3N3]3− .

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Article information

DOI
https://doi.org/10.1039/A908954C
Article type
Communication
Submitted
10 Nov 1999
Accepted
26 Jan 2000
First published
22 Feb 2000

Chem. Commun., 2000, 341-342

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cis-Trihydrogen cyclotriphosphazenates—acidic anions in strongly basic media

G. T. Lawson, F. Rivals, M. Tascher, C. Jacob, J. F. Bickley and A. Steiner, Chem. Commun., 2000, 341 DOI: 10.1039/A908954C

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