Issue 2, 2000

A direct conversion of α,β-unsaturated ketones to vinylcyclopropanes: new zirconium-mediated reaction

Abstract

Various vinylcyclopropanes are synthesized from α,β-unsaturated ketones via a zirconium-mediated [1,2]-addition–deoxygenative cyclopropanation sequence; the latter step surprisingly proceeds under specific protic conditions.

Article information

Article type
Paper

Chem. Commun., 2000, 171-172

A direct conversion of α,β-unsaturated ketones to vinylcyclopropanes: new zirconium-mediated reaction

P. Bertus, V. Gandon and J. Szymoniak, Chem. Commun., 2000, 171 DOI: 10.1039/A908897K

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