Issue 5, 2000
From the journal:

Chemical Communications

Oxidative N-demethylation of N,N-dimethylanilines catalysed by lignin peroxidase: a mechanistic insight by a kinetic deuterium isotope effect study

Enrico Baciocchi,*a   Maria Francesca Gerini,b   Osvaldo Lanzalunga,b   Andrea Lapi,b   Simona Mancinellib  and  Paolo Mencarellib  

* Corresponding authors

a Dipartimento di Chimica, Università ‘La Sapienza’, P.le A. Moro 5, Rome, Italy.
E-mail: baciocchi@axcasp.caspur.it

b Dipartimento di Chimica and Centro CNR di Studio sui Meccanismi di Reazione, Università ‘La Sapienza’, P.le A. Moro 5, Rome, Italy

Abstract

Lignin peroxidase can catalyse the N-demethylation of N,N-dimethylanilines by an electron transfer mechanism, where the deprotonation of the intermediate radical cation is also an enzymatic process.

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Article information

DOI
https://doi.org/10.1039/A908394D
Article type
Communication
Submitted
18 Oct 1999
Accepted
13 Jan 2000
First published
25 Feb 2000

Chem. Commun., 2000, 393-394

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Oxidative N-demethylation of N,N-dimethylanilines catalysed by lignin peroxidase: a mechanistic insight by a kinetic deuterium isotope effect study

E. Baciocchi, M. F. Gerini, O. Lanzalunga, A. Lapi, S. Mancinelli and P. Mencarelli, Chem. Commun., 2000, 393 DOI: 10.1039/A908394D

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