Issue 5, 2000
From the journal:

Chemical Communications

A convenient synthesis of porphodimethenes and their conversion to trans-porphyrins with two functionalized meso-naphthyl substituents

Michael Harmjanza  and  Michael J. Scotta  

a Department of Chemistry, University of Florida, Gainesville, FL, USA.
E-mail: mjscott@chem.ufl.edu

Abstract

The Mac Donald-type 2 + 2 condensation of the readily available 5-mesityldipyrromethane with acenaphthenequinone leads to the trans (syn and anti) porphodimethenes, respectively, which, after treatment with KOH or NaOMe in THF and subsequent oxidation with air, yield the corresponding trans-8-carboxynaphthylporphyrins or their esters.

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Article information

DOI
https://doi.org/10.1039/A907992K
Article type
Communication
Submitted
04 Oct 1999
Accepted
20 Jan 2000
First published
25 Feb 2000

Chem. Commun., 2000, 397-398

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A convenient synthesis of porphodimethenes and their conversion to trans-porphyrins with two functionalized meso-naphthyl substituents

M. Harmjanz and M. J. Scott, Chem. Commun., 2000, 397 DOI: 10.1039/A907992K

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