Issue 12, 1999

Photochemical addition of secondary alcohols to maleimides

Abstract

Under UV irradiation, propan-2-ol adds to the C[double bond, length half m-dash]C bond of maleimides 4 to give 2-(1-hydroxy-1-methylethyl)succinimides 5 in 25–70% yield. Cyclohexanol adds in the same way to give 2-(1-hydroxycyclohexyl)succinimides 6. Several trace by-products are identified by GC-MS analysis and their formation accounted for.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1999, 2667-2670

Photochemical addition of secondary alcohols to maleimides

M. A. S. Al-Amoudi and J. M. Vernon, J. Chem. Soc., Perkin Trans. 2, 1999, 2667 DOI: 10.1039/A907517H

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