Jump to main content
Jump to site search

Issue 7, 1999
Previous Article Next Article

Influence of solvent polarity on the photoreactivity of 2–4-ring aromatic o-quinones

Abstract

The solvent polarity dependence of the photoreactivity of naphthalene-1,2-dione (1), acenaphthylene-1,2-dione (2), phenanthrene-9,10-dione (3), and aceanthrylene-1,2-dione (4) was investigated by means of nanosecond laser-flash photolysis techniques. The reactivity of the triplets of 1, 2, and 3 towards hydrogen abstraction increases as the polarity of the solvent decreases owing to an inversion between n,π* and π,π* triplet states relatively close in energy. The relative increase in triplet reactivity follows the order 2 < 3 < 1. In the case of 4 no inversion of triplet levels is detected; the lowest excited triplet state of 4 is π,π* in character in both polar and nonpolar solvents.

Back to tab navigation

Article information


J. Chem. Soc., Perkin Trans. 2, 1999, 1439-1442
Article type
Paper

Influence of solvent polarity on the photoreactivity of 2–4-ring aromatic o-quinones

M. Barra, E. D. Harder and J. P. Balfe, J. Chem. Soc., Perkin Trans. 2, 1999, 1439
DOI: 10.1039/A900760A

Search articles by author

Spotlight

Advertisements