Issue 21, 1999
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Highly chemoselective α-diazo carbonyl insertion reactions into N–H and S–H bonds catalysed by [RuCl(η5-C5H5)(PPh3)2]

Alessandro Del Zotto,   Walter Baratta  and  Pierluigi Rigo  

Abstract

Complex [RuCl(η5-C5H5)(PPh3)2], in chloroform at 60 °C, catalyses the chemoselective insertion of α-diazo carbonyl compounds into N–H and S–H bonds to afford α-keto-amines and α-keto-thioethers.

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Article information

DOI
https://doi.org/10.1039/A906332C
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 3079-3081

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Highly chemoselective α-diazo carbonyl insertion reactions into N–H and S–H bonds catalysed by [RuCl(η5-C5H5)(PPh3)2]

A. Del Zotto, W. Baratta and P. Rigo, J. Chem. Soc., Perkin Trans. 1, 1999, 3079 DOI: 10.1039/A906332C

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