Issue 20, 1999

Synthetic utility of 1,1,2,2-tetraaryldisilanes: radical reduction of alkyl phenyl chalcogenides

Abstract

Reactivity of tetraaryldisilanes as radical reducing agents of alkyl phenyl chalcogenides initiated by Et3B or AIBN was studied. Here, the reactivity of alkyl sulfide was poor; however, various alkyl phenyl selenides and tellurides were reduced to the corresponding hydrocarbons in good yields with 1,1,2,2-tetraphenyldisilane.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 2891-2896

Synthetic utility of 1,1,2,2-tetraaryldisilanes: radical reduction of alkyl phenyl chalcogenides

O. Yamazaki, H. Togo and M. Yokoyama, J. Chem. Soc., Perkin Trans. 1, 1999, 2891 DOI: 10.1039/A905937G

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