Epoxides from α,β-unsaturated ketones undergo highly chemo- and regioselective rearrangement to 1,3-dicarbonyl compounds in 5 mol dm–3 lithium perchlorate–diethyl ether medium by a 1,2-migration of the carbonyl group at ambient conditions.
S. Sankararaman and J. E. Nesakumar, J. Chem. Soc., Perkin Trans. 1, 1999, 3173 DOI: 10.1039/A905619J
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