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Issue 24, 1999
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Aminosilylation of aldehydes mediated by lithium perchlorate: novel method for synthesis of α-silylamines

Abstract

α-Silylated N,N-dialkylamines 7a–k were easily synthesized in good to excellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phenyldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilyllithium 6, in concentrated ethereal lithium perchlorate solution.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1999, 3709-3711
Article type
Paper

Aminosilylation of aldehydes mediated by lithium perchlorate: novel method for synthesis of α-silylamines

M. Reza Naimi-Jamal, M. M. Mojtahedi, J. Ipaktschi and M. R. Saidi, J. Chem. Soc., Perkin Trans. 1, 1999, 3709
DOI: 10.1039/A904498A

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