SCHEDULED MAINTENANCE
A concise stereocontrolled construction of taxane CB-ring system (C→CB) is described. The key bottom and top linking of the eight-membered B-ring were realized unprecedentedly by way of successive intermolecular aldol condensation and intramolecular aldol cyclization.
C. Wei, G. Zhao, X. Jiang and Y. Ding, J. Chem. Soc., Perkin Trans. 1, 1999, 3531 DOI: 10.1039/A904382I
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