Issue 20, 1999

Anionic [4 + 2] cycloaddition reactions of dihydropyrazolin-5-one dienolate with dienophiles: a novel approach for substituted and fused indazolones

Abstract

Dihydropyrazolin-5-one dienolate 2 generated by deprotonation of 2,3-dimethyl-4-formyl-1-phenylpyrazolin-5-one (4-formylantipyrine) is shown to be an efficient anionic pyrazolone α-oxy-o-quinodimethane analog, which undergoes facile cycloaddition with a variety of dienophiles to give substituted indazolones in good yields after dehydration–dehydrogenation of cycloadducts.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 3001-3004

Anionic [4 + 2] cycloaddition reactions of dihydropyrazolin-5-one dienolate with dienophiles: a novel approach for substituted and fused indazolones

A. Roy, K. R. Reddy, H. Ila and H. Junjappa, J. Chem. Soc., Perkin Trans. 1, 1999, 3001 DOI: 10.1039/A903710A

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