Cyclic sulfamidates function as excellent precursors to a variety of unnatural α,α-disubstituted amino acid derivatives by ring opening with a suitable nucleophile. Addition of various nucleophiles to a sulfamidate derived from 2-methylserine is described.
L. T. Boulton, H. Thijs Stock, J. Raphy and D. C. Horwell, J. Chem. Soc., Perkin Trans. 1, 1999, 1421 DOI: 10.1039/A901667H
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