The structure of triticusterol isolated from the germ oil of wheat (Triticum aestivum L.; Gramineae) was established to be 4α-methyl-5α,14β-ergosta-8,24(241)-dien-3β-ol on the basis of spectroscopic data. This is the first example of a naturally occurring compound with a 14β(H)-steroid skeleton.
T. Akihisa, W. C. M. C. Kokke, K. Koike, Y. Kimura, C. Mizukami, A. Sadaie, T. Maruyama and T. Nikaido, J. Chem. Soc., Perkin Trans. 1, 1999, 497 DOI: 10.1039/A808508K
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