Issue 9, 1999

Structural diversity in nonafluoromesityl chemistry

Abstract

Several new compounds containing the nonafluoromesityl substituent [2,4,6-tris(trifluoromethyl)phenyl, abbreviated as RF] have been prepared and structurally characterized. Solid state structures are reported for C5Me5P(Cl)RF (1), Sn(SeRF)4 (3), Te(RF)2 (4) and (AgRF)4 (5). 1 and 4 crystallize in space group P21/c, 3 in space group P[1 with combining macron], and 5 in space group I41/a. While 1 and 3 are monomeric in the solid state, the telluride 4 is dimerized via Te···F secondary bonds and 5 adopts a tetrameric structure containing a central Ag4 ring. Furthermore the preparation of C5Me5P(H)RF (2) is described.

Supplementary files

Article information

Article type
Paper

New J. Chem., 1999,23, 905-909

Structural diversity in nonafluoromesityl chemistry

H. Voelker, D. Labahn, F. Michael Bohnen, R. Herbst-Irmer, H. W. Roesky, D. Stalke and F. T. Edelmann, New J. Chem., 1999, 23, 905 DOI: 10.1039/A903798E

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