Issue 1, 1999
From the journal:

New Journal of Chemistry

What are the primary products of reactions between anionic hydrides and HCCPh?

Brandon Reinhart  and  Dmitry G. Gusev  

Abstract

Reactions of phenylacetylene with [RuH2(CO)L]- [L is the pincer ligand C6H3-2,6-(CH2PBu2t)2], [RuH3(CO)(PPr3i)2]- and [ReH3(NO)(PPr3i)2]- have afforded the new anionic σ-alkynyl and vinyl complexes trans-[RuH(CCPh)(CO)L]-, cis-[RuH2(CCPh)(CO)(PPr3i)2]-, cis-[RuH2(CPhξCH2)- (CO)(PPr3i)2]- and cis-[ReH2(CPhξCH2)(NO)(PPr3i)2]-, all as the [K(18-crown-6)]+ salts. Formation of the acetylides does not involve unsaturated species and takes place via [MνC(Ph)ξCH2] vinyl intermediates.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A807554I
Article type
Paper

New J. Chem., 1999,23, 1-3

Permissions

Request permissions

What are the primary products of reactions between anionic hydrides and HCCPh?

B. Reinhart and D. G. Gusev, New J. Chem., 1999, 23, 1 DOI: 10.1039/A807554I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements