The C–H activation of an NMe2 group in diaminocarane coordinated to an Os3 cluster results in the formation of (R,S)-{Os3(CO)10(µ- H){µ,η2(N,C)- (4R,6R,8S,10S)-1,7,7,10-tetramethyl-1,3- diazatricyclo[3.5.0.0]dec-1-en-2-yl}} diastereomers.
V. A. Maksakov, V. P. Kirin, A. V. Virovets, P. A. Petukhov and A. V. Tkachev, Mendeleev Commun., 1999, 9, 213 DOI: 10.1070/MC1999v009n06ABEH001128
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