The mechanism of oxidative dihydrogen addition to palladium clusters has been analysed in terms of the reaction-path Hamiltonian approximation, and the abnormal H/D kinetic isotope effect has been explained.
V. M. Mamaev, I. P. Gloriozov, A. V. Prisyajnyuk and Y. V. Babin, Mendeleev Commun., 1999, 9, 136 DOI: 10.1070/MC1999v009n04ABEH001094
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