1,2-H-Diaziridines can be successfully alkylated only at one of the ring nitrogen atoms, whereas preliminary metalation is required for introducing an alkyl substituent at the second nitrogen atom; this metalation was performed using N-sodium salts as an example.
N. N. Makhova, G. A. Karpov, A. N. Mikhailyuk and L. I. Khmel'nitskii, Mendeleev Commun., 1999, 9, 112 DOI: 10.1070/MC1999v009n03ABEH001121
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