Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium gives strained cyclic allene 1 containing an ethenylidene-cyclopropane unit in a nine-membered ring and dimer 6 resulting from a dibromotriangulane rearrangement.
E. B. Averina, T. S. Kuznetsova, A. N. Zefirov, A. E. Koposov, N. S. Zefirov, Y. A. Grishin and N. S. Zefirov, Mendeleev Commun., 1999, 9, 101 DOI: 10.1070/MC1999v009n03ABEH001078
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