Interaction of olefin–NO+ complexes: structure and dynamics of the NO+–2,3-dimethyl-2-butene complex
Abstract
1H and 13C NMR studies involving the 13C NMR deuterium perturbation method and ab initio calculations showed the interaction between 2,3-dimethyl-2-butene and the nitrosonium cation to form a dynamic π-complex.