Based on ethyl (S)-(–)-lactate, an original sequence of highly stereoselective transformations leading to (4S,5E)-4-bromomethyl-hept-5-enenitrile was developed using rearrangement of a chiral cyclopropyl carbinol as the key step.
M. V. Zlokazov and V. V. Veselovskii, Mendeleev Commun., 1999, 9, 73 DOI: 10.1070/MC1999v009n02ABEH000882
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