Issue 2, 1999

Synthesis and structure of stable chiral AuI complexes with N,N'-diaryl-α-naphthamidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides

Abstract

Novel N-amidine-functionalized cyclopentadiene gold(i) complexes [C5(CO2Me)4{ArNC(α-C110H7)NAr}]Au(PPh3) have been prepared, and their stable chiral structure with the Au-N bond [2.091(6) Å] and the additional coordination Au‥π-system of the cyclopentadiene ring has been proved by X-ray crystallography and NMR spectroscopy.

Article information

Article type
Paper

Mendeleev Commun., 1999,9, 67-70

Synthesis and structure of stable chiral AuI complexes with N,N'-diaryl-α-naphthamidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides

G. A. Dushenko, I. E. Mikhailov, A. Zschunke, G. Reck, B. Schulz, C. Mugge and V. I. Minkin, Mendeleev Commun., 1999, 9, 67 DOI: 10.1070/MC1999v009n02ABEH001064

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