Issue 4, 1999

Structural and electrical properties of bis(ethylenedithio)tetrathiafulvalenium hydrogen fumarate (2/1): a BEDT-TTF mixed-valency salt with a hydrogen-bonding organic anion

Abstract

Electro-oxidation of BEDT-TTF in the presence of tetrabutylammonium hydrogen fumarate affords the salt (BEDT-TTF) 2 [(E)-HO 2 C-CH=CH-CO 2 ], in which the BEDT-TTF units adopt a β-type packing and the organic anions form infinite chains by hydrogen-bonding; this salt is a semiconductor and its room-temperature conductivity is ca. 3 S cm –1 .

Article information

Article type
Paper

J. Mater. Chem., 1999,9, 851-853

Structural and electrical properties of bis(ethylenedithio)tetrathiafulvalenium hydrogen fumarate (2/1): a BEDT-TTF mixed-valency salt with a hydrogen-bonding organic anion

M. Giffard, A. Riou, G. Mabon, N. Mercier, P. Molinié and T. Phap Nguyen, J. Mater. Chem., 1999, 9, 851 DOI: 10.1039/A810002K

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