The kinetics of decomposition of hydrazine and hydroxylamine in concentrated nitric acid at 70°C establish a critical concentration [hydrazine]≈5×10–4 mol dm–3 below which a rapid autocalalytic decomposition of hydroxylamine occurs; this corresponds to the rate of nitrite scavenging by hydrazine balancing the rate of N2O4 formation.
G. C. M. Bourke and G. Stedman, J. Chem. Res. (S), 1999, 684 DOI: 10.1039/A905995D
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