SCHEDULED MAINTENANCE
The transannular directing effect of a 2α,3α-, 2β,3β- and 5α,6α-epoxide on the epoxidation of a 5-ene and a 2-ene, respectively, is shown to increase the proportion of epoxidation of the anti face of the alkene when compared to the unsubstituted 2- and 5-androstenes.
J. R. Hanson, P. B. Hitchcock and I. Kiran, J. Chem. Res. (S), 1999, 538 DOI: 10.1039/A902935D
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