The Pauson–Khand reaction on suitable carbohydrate derivatives obtained from L-arabinose gives annulated pyranosides that can be transformed into advanced synthetic intermediates for the synthesis of iridoid aglycones. Preliminary studies towards this end are described.
J. Marco-Contelles and J. Ruiz, J. Chem. Res. (S), 1999, 260 DOI: 10.1039/A809425J
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