SCHEDULED MAINTENANCE
β-Amino-α-hydroxyacids (norstatines) are prepared from urethane N-protected carboxyanhydrides (UNCAs); the key step is the diastereoselective reduction of a keto-acetylenic compound, which lead is, with syn diastereoselectivity, to the corresponding propargylic alcohol.
P. Audin, C. Pothion, J. Fehrentz, A. Loffet, J. Martinez and J. Paris, J. Chem. Res. (S), 1999, 282 DOI: 10.1039/A809421G
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