Issue 2, 1999

Synthesis of α-Phenylthioacylmethylene Triphenylarsoranes and their Wittig-type Reactions

Abstract

α-Phenylthio acylmethylene triphenylarsoranes, the first stable α-thiyl arsonium ylides, are prepared by phenylsulfenylation–transylidation reaction of the corresponding acylmethylene triphenylarsoranes with phenylsulfenyl chloride; Wittig reactions are carried out under mild reaction conditions on the arsonium ylides to provide α-phenylthio-α,β-unsaturated ketones.

Article information

Article type
Paper

J. Chem. Res. (S), 1999, 144-145

Synthesis of α-Phenylthioacylmethylene Triphenylarsoranes and their Wittig-type Reactions

G. Deng, Z. Huang, X. Yu and X. Huang, J. Chem. Res. (S), 1999, 144 DOI: 10.1039/A807764I

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