A correlation between the position of the 13C NMR signal for the C-10 methyl group (C-19) and the stereochemistry of the A/B ring junction has been established and applied to the determination of the stereochemistry of the products of the hydroboration of B-norandrosta-3,5-dien-17-one.
J. R. Hanson, P. B. Hitchcock, V. Thangavelu and C. Uyanik, J. Chem. Res. (S), 1999, 18 DOI: 10.1039/A806378H
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