Issue 21, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

β-Hydride shift involvement in the acid catalysed decomposition of [(H2O)5CrIII–C(CH3)2OH]2+

Nurit Shaham,   Haim Cohen  and  Dan Meyerstein  

Abstract

Propene has been found to be a major product of the acid catalysed decomposition of [(H2O)5CrIII–C(CH3)2OH]2+. It is proposed that this complex isomerizes via a β-hydride shift step to form [(H2O)5CrIII–CH2CH(CH3)OH]2+ which decomposes via β-hydroxide elimination.

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Article information

DOI
https://doi.org/10.1039/A905674B
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 3805-3808

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β-Hydride shift involvement in the acid catalysed decomposition of [(H2O)5CrIII–C(CH3)2OH]2+

N. Shaham, H. Cohen and D. Meyerstein, J. Chem. Soc., Dalton Trans., 1999, 3805 DOI: 10.1039/A905674B

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