Issue 17, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, structural characterization and catalytic properties of a novel monomeric rhenium(V)methyl(oxo)bis(η2-picolinato) complex: [CH3Re(O)(pic)2] †

Alexis Deloffre,   Sabine Halut,   Laurent Salles,   Jean-Marie Brégeault,   José Ribeiro Gregorio,   Bernard Denise  and  Henri Rudler  

Abstract

A methyl mono-oxo rhenium(V) complex with two picolinato chelating ligands has been synthesized and structurally characterized. When reacted with excess 10 or 30% H2O2 it forms peroxo species responsible for the catalytic activity of a highly selective two-phase medium.

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Article information

DOI
https://doi.org/10.1039/A904952E
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 2897-2898

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Synthesis, structural characterization and catalytic properties of a novel monomeric rhenium(V)methyl(oxo)bis(η2-picolinato) complex: [CH3Re(O)(pic)2] †

A. Deloffre, S. Halut, L. Salles, J. Brégeault, J. Ribeiro Gregorio, B. Denise and H. Rudler, J. Chem. Soc., Dalton Trans., 1999, 2897 DOI: 10.1039/A904952E

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