Issue 15, 1999

Synthesis and structure of 2,2′-biphosphirenes

Abstract

The reaction of an excess of the transient terminal phosphinidene complex [PhP→W(CO)5] with selected 1,3-diynes at 110 °C in toluene affords the corresponding 2,2′-biphosphirene–W2(CO)10 complexes as a 1∶1 meso + rac mixture; according to the X-ray crystal structure analysis of one of the rac-complexes, some delocalisation takes place within the diene sub-unit of these biphosphirenes.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 2409-2410

Synthesis and structure of 2,2′-biphosphirenes

N. Hoa Tran Huy, L. Ricard and F. Mathey, J. Chem. Soc., Dalton Trans., 1999, 2409 DOI: 10.1039/A904150H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements