The preparation and crystal structure of the first complex of a multidentate, fac-[Mn(CO)3{MeC(CH2-TeMe)3}]CF3SO3 are described, and multinuclear NMR spectroscopic studies suggest that the telluroether is a significantly better σ-donor to Mn(I compared to its selenoether analogue.
W. Levason, S. D. Orchard and G. Reid, J. Chem. Soc., Dalton Trans., 1999, 823 DOI: 10.1039/A900615J
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