Synthesis and structural characterisation of the novel tetranuclear cluster compound [Pd4(µ-SO2)2(µ3-S)(CO)(PBz3)4] (Bz = C6H5CH2)
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Abstract
The synthesis, spectroscopic charcterisation and single crystal structure are reported for the novel tetranuclear cluster compound [Pd4(µ-SO2)2(µ3-S(CO)(PBz3)4], obtained when[Pd2(µ-dba)(µSO2)(PBz3)2] dba = dibenzylideneacetone, Bz = benzyl) is reacted with COS which fragments to give independent CO and S ligands on a tetrahedral cluster.
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