Issue 5, 1999

Synthesis and structural characterisation of the novel tetranuclear cluster compound [Pd4(µ-SO2)23-S)(CO)(PBz3)4] (Bz = C6H5CH2)

Abstract

The synthesis, spectroscopic charcterisation and single crystal structure are reported for the novel tetranuclear cluster compound [Pd4(µ-SO2)23-S(CO)(PBz3)4], obtained when[Pd2(µ-dba)(µSO2)(PBz3)2] dba = dibenzylideneacetone, Bz = benzyl) is reacted with COS which fragments to give independent CO and S ligands on a tetrahedral cluster.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 653-654

Synthesis and structural characterisation of the novel tetranuclear cluster compound [Pd4(µ-SO2)23-S)(CO)(PBz3)4] (Bz = C6H5CH2)

S. V. Tarlton, N. Choi, M. McPartlin, D. Michael P. Mingos and R. Vilar, J. Chem. Soc., Dalton Trans., 1999, 653 DOI: 10.1039/A810016K

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