Issue 2, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Self-assembling copper(I) clusters involving electron-deficient, quadruply bridging thiolate ligands

Robin G. Prichard,   R. V. Parish  and  Zahra Salehi  

Abstract

The structures of two new compounds containing the Cu12(µ4-S)6 Atlas-sphere cluster have been determined: (CuBr)13(SR)6·xH2O (x = ca. 1.5) and (CuCl)17(SR′)6 (SR = CH2CH2NH3, SR′ = CH2CH2NHMe2). The zwitterionic ligands are unique amongst simple thiolates in forming µ4 bridges between four metal ions. The formation of these materials from solutions which contain an excess of the thiolate is discussed.

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DOI
https://doi.org/10.1039/A808125E
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 243-250

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Self-assembling copper(I) clusters involving electron-deficient, quadruply bridging thiolate ligands

R. G. Prichard, R. V. Parish and Z. Salehi, J. Chem. Soc., Dalton Trans., 1999, 243 DOI: 10.1039/A808125E

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