Issue 1, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

N,N ′,N ″-Triphenylguanidinate(1–) complexes of ruthenium and palladium: syntheses and crystal structures †

K. Travis Holman,   Stephen D. Robinson,   Arvind Sahajpal  and  Jonathan W. Steed  

Abstract

N,N ′,N ″ -Triphenylguanidine (HTpg) reacted with [Ru(O2CCF3)2(CO)(PPh3)2] in boiling toluene to yield [Ru(Tpg)2(CO)(PPh3)], the first example of a mononuclear complex containing two chelate guanidinate(1–) ligands. Palladium(II) acetate reacted with HTpg in warm benzene to form an adduct [Pd(O2CMe)2(HTpg)2] which, under more forcing conditions, converts into the novel binuclear guanidinate(1–) bridged complex [{Pd(µ-Tpg)(Tpg)}2]. Crystal structures have been determined for both guanidinate(1–) complexes.

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Article information

DOI
https://doi.org/10.1039/A806454G
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 15-18

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N,N ′,N ″-Triphenylguanidinate(1–) complexes of ruthenium and palladium: syntheses and crystal structures †

K. Travis Holman, S. D. Robinson, A. Sahajpal and J. W. Steed, J. Chem. Soc., Dalton Trans., 1999, 15 DOI: 10.1039/A806454G

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