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Issue 19, 1999
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Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins

Abstract

IR spectroscopic results, combined with earlier crystallographic and spectroscopic evidence on Fe and Ru nitrosyl complexes, indicate that metastable η1-O and η2-NO linkage isomers are formed on low-temperature irradiation of the nitrosyl metalloporphyrins (OEP)Ru(NO)L (L = O-i-C5H11, SCH2CF3); the new compounds are stable at low temperature, but revert to the ground state on warming.

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Article information


Chem. Commun., 1999, 2013-2014
Article type
Paper

Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins

D. V. Fomitchev, P. Coppens, T. Li, K. A. Bagley, L. Chen and G. B. Richter-Addo, Chem. Commun., 1999, 2013
DOI: 10.1039/A905285B

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