SCHEDULED MAINTENANCE
According to the protocol for the acetalization–intramolecular allylsilane cyclization, a new enantioenriched allylsilane, (R)-(E)-7-(dimethylphenylsilyl)undec-5-en-1-ol, in the presence of a variety of aldehydes provided enantioenriched trans-2,3-disubstituted oxepanes stereoselectively.
M. Suginome, T. Iwanami and Y. Ito, Chem. Commun., 1999, 2537 DOI: 10.1039/A908603J
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