The complex Rh(PPh3)3Cl immobilized on MCM-41 modified with (OEt)3Si(CH2)3PPh2 results in a stable hydrogenation catalyst with turnover frequency (TOF) three times higher than that of Rh(PPh3)3Cl in the hydrogenation of cyclohexene.
S. Shyu, S. Cheng and D. Tzou, Chem. Commun., 1999, 2337 DOI: 10.1039/A907207A
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