A new bifunctional ligand: C5Me4SiMe2OSiMe2O2–. Synthesis, properties and crystal structure of the first Yb(II) half-sandwich complex with a heterobidentate cyclopentadienyl ligand, [{(η5-C5Me4)SiMe2OSiMe2(η1-O)}Yb(thf)]2
Abstract
The synthesis and crystal structure of the Yb(II) half-sandwich complex [{(η5-C5Me4)SiMe2OSiMe2(η1-O)}Yb(thf)]2 containing the new linked tetramethylcyclopentadienyl-silanolate ligand C5Me4SiMe2OSiMe2O2– are reported.