Cyclodepolymerisation of functional linear polyesters gives macrocycles which, on equilibration via transesterification, give soluble combinatorial libraries of crown ether-ester analogues, one consisting of 30 different 18- or 27-membered rings and another consisting of 29 different 24- or 36-membered rings.
P. Monvisade, P. Hodge and C. L. Ruddick, Chem. Commun., 1999, 1987 DOI: 10.1039/A905685H
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