Issue 18, 1999

Macropolyhedral boron-containing cluster chemistry. The [SB17H19] anion: a nido-ten-vertex : arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane

Abstract

Reaction of syn-B18H22 with metabisulfite gives a good yield of the first single-sulfur macropolyhedral thiaborane, the [SB17H19] anion, which exhibits the unusual arachnonido two-borons-in-common cluster fusion mode.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1905-1906

Macropolyhedral boron-containing cluster chemistry. The [SB17H19] anion: a nido-ten-vertex : arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane

T. Jelínek, C. A. Kilner, S. A. Barrett, M. Thornton-Pett and J. D. Kennedy, Chem. Commun., 1999, 1905 DOI: 10.1039/A905473A

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