(1,3,5)Pyridinophanes having [4.3.2]propellatriene units were synthesized as precursors to macrocyclic polyyne C58H4N2; diazafullerene anion C58N2– was detected in the laser desorption mass spectrum of the pyridinophanes.
Y. Tobe, H. Nakanishi, M. Sonoda, T. Wakabayashi and Y. Achiba, Chem. Commun., 1999, 1625 DOI: 10.1039/A905207K
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