Issue 15, 1999
From the journal:

Chemical Communications

Formamides undergo in-plane bimolecular nucleophilic vinylic substitutions (SN2) by the reaction with (E)-alkenyl(phenyl)iodonium tetrafluoroborates: stereoselective synthesis of (Z)-vinyl formates

Masahito Ochiai,   Shinji Yamamoto  and  Koichi Sato  

Abstract

Reported for the first time is the stereoselective synthesis of (Z)-vinyl formates, which involves in-plane bimolecular nucleophilic vinylic substitutions of (E)-β-alkylvinyl(phenyl)iodonium tetrafluoroborates with formamides.

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Article information

DOI
https://doi.org/10.1039/A904220B
Article type
Paper

Chem. Commun., 1999, 1363-1364

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Formamides undergo in-plane bimolecular nucleophilic vinylic substitutions (SN2) by the reaction with (E)-alkenyl(phenyl)iodonium tetrafluoroborates: stereoselective synthesis of (Z)-vinyl formates

M. Ochiai, S. Yamamoto and K. Sato, Chem. Commun., 1999, 1363 DOI: 10.1039/A904220B

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