The first heterobimetallic organolanthanide complex containing two different rare earth elements, [Yb(thf)6][Ce- (cot′′′)2]2 2 [cot′′′ = η8-1,3,6-(Me3Si)3C8H5], has been prepared by reacting neutral [Ce(cot′′′)2] with Yb metal in THF; the crystal structure of 2 consists of separated [Yb(thf)6]2+ and [Ce(cot′′′)2]– ions.
U. Reißmann, P. Poremba, L. Lameyer, D. Stalke and F. T. Edelmann, Chem. Commun., 1999, 1865 DOI: 10.1039/A903954F
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