The carbonylation of aryl halides catalysed by CO2 soluble Pd complexes with trialkyl or triaryl phosphite ligands proceeds rapidly in scCO2, in which the rate of the reaction is higher than those attained in solution phase reactions.
Y. Kayaki, Y. Noguchi, S. Iwasa, T. Ikariya and R. Noyori, Chem. Commun., 1999, 1235 DOI: 10.1039/A902942G
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