A highly stereocontrolled 1,2-cis-α-glycosidation reaction under conditions mild enough for acid-labile alcohols has been developed using benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors in the presence of 2,6-di-tert-butylpyridinium iodide and tetrabutylammonium iodide.
H. Tanaka, H. Sakamoto, A. Sano, S. Nakamura, M. Nakajima and S. Hashimoto, Chem. Commun., 1999, 1259 DOI: 10.1039/A902845E
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