Complexes of the fluorescent crown ether, N,N-bis(9-anthrylmethyl)-4,13-diaza-18-crown-6, with NaI3 and KSCN reveal the presence of intramolecular C–H‥O hydrogen bonds that appear to control conformation and lead to reduced cation binding affinity.
S. L. De Wall, E. S. Meadows, L. J. Barbour and G. W. Gokel, Chem. Commun., 1999, 1553 DOI: 10.1039/A902676B
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